specific corrosion mechanisms that Hastelloy C-276 can resist in phosphoric acid production
specific corrosion mechanisms that Hastelloy C-276 can resist in phosphoric acid production
22nd June 2024
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specific corrosion mechanisms that Hastelloy C-276 can resist in phosphoric acid production
1.Phosphoric Acid Corrosion:
Phosphoric acid is a highly corrosive medium, particularly at elevated temperatures and concentrations commonly encountered in phosphoric acid production.
Hastelloy C-276 exhibits outstanding resistance to general corrosion in phosphoric acid due to the formation of a protective chromium-rich passive film on the alloy surface.
This passive film effectively shields the underlying alloy from direct attack by the phosphoric acid, even at high temperatures and concentrations.
Pitting Corrosion:
Phosphoric acid can be prone to inducing localized pitting corrosion on many alloys, particularly in the presence of impurities or contaminants.
Hastelloy C-276's high molybdenum content and balanced alloying composition provide superior resistance to pitting corrosion in phosphoric acid environments.
The molybdenum helps to stabilize the passive film and prevent the initiation and propagation of pits.
Crevice Corrosion:
Crevice corrosion is a common concern in phosphoric acid production equipment, where tight clearances and design features can create crevices susceptible to localized corrosion.
Hastelloy C-276 demonstrates excellent resistance to crevice corrosion in phosphoric acid, thanks to its ability to maintain a protective passive film even in confined, stagnant areas.
Stress Corrosion Cracking:
The combination of tensile stresses and the corrosive phosphoric acid environment can lead to stress corrosion cracking in some alloys.
Hastelloy C-276's balanced nickel, chromium, and molybdenum content, along with its high work hardening rate, contribute to its superior resistance to stress corrosion cracking in phosphoric acid.
High-Temperature Corrosion:
Phosphoric acid production often involves elevated temperatures, which can exacerbate corrosion rates in many materials.
Hastelloy C-276 maintains its excellent corrosion resistance even at the high temperatures typical of phosphoric acid production processes, thanks to its stable passive film and high-temperature mechanical properties.