specific corrosion mechanisms that Hastelloy C-276 can resist in phosphoric acid production

specific corrosion mechanisms that Hastelloy C-276 can resist in phosphoric acid production
  • 22nd June 2024
  • admin

specific corrosion mechanisms that Hastelloy C-276 can resist in phosphoric acid production

 

         1.Phosphoric Acid Corrosion:

      • Phosphoric acid is a highly corrosive medium, particularly at elevated temperatures and concentrations commonly encountered in phosphoric acid production.
      • Hastelloy C-276 exhibits outstanding resistance to general corrosion in phosphoric acid due to the formation of a protective chromium-rich passive film on the alloy surface.
      • This passive film effectively shields the underlying alloy from direct attack by the phosphoric acid, even at high temperatures and concentrations.
    1. Pitting Corrosion:

      • Phosphoric acid can be prone to inducing localized pitting corrosion on many alloys, particularly in the presence of impurities or contaminants.
      • Hastelloy C-276's high molybdenum content and balanced alloying composition provide superior resistance to pitting corrosion in phosphoric acid environments.
      • The molybdenum helps to stabilize the passive film and prevent the initiation and propagation of pits.
    2. Crevice Corrosion:

      • Crevice corrosion is a common concern in phosphoric acid production equipment, where tight clearances and design features can create crevices susceptible to localized corrosion.
      • Hastelloy C-276 demonstrates excellent resistance to crevice corrosion in phosphoric acid, thanks to its ability to maintain a protective passive film even in confined, stagnant areas.
    3. Stress Corrosion Cracking:

      • The combination of tensile stresses and the corrosive phosphoric acid environment can lead to stress corrosion cracking in some alloys.
      • Hastelloy C-276's balanced nickel, chromium, and molybdenum content, along with its high work hardening rate, contribute to its superior resistance to stress corrosion cracking in phosphoric acid.
    4. High-Temperature Corrosion:

      • Phosphoric acid production often involves elevated temperatures, which can exacerbate corrosion rates in many materials.
      • Hastelloy C-276 maintains its excellent corrosion resistance even at the high temperatures typical of phosphoric acid production processes, thanks to its stable passive film and high-temperature mechanical properties.